Manuchar Chiqovani


Synthesis and of cyanide complexes of cuprum (I) to arsenic ligands is represented. We took arsenic iodide absolute alcohol (spirit) as
arsenic ligands, which was taken to the admixture with the influence of the solution (in water) of plumbic nitrate by this general
formula where which was added to potassium dicyandiamide (I) water
solution and cryptocrystalline substance, which was filtered according to the rules after maturing mother chemical solution and we
made an analysis to it. Into the mixed substances we determined arsenic by Evinss method, and cuprum by the method of
iodometry, we determined the coordinated formulas of the synthesized complex admixtures by analyzing electric conductivity of the
diluted solutions in dimethyl-formamide solution. The outcomes of the research confirm that mixed (synthesized) admixtures are
cationic-anionic complexes. The consistence and structure of synthesized compounds (admixture) were also established with the
methods of spectroscopy and X-ray analysis. Transforming of the complexes towards heating is searched by thermo-graphic method.
Synthesized (compound) complexes reveal biocide chemical influence towards the studied actinomyces.
Aim: The aim of this work is to make a research of the synthesis of tri aril- alkilarsonium dicyanoargentates and determine their
physical and chemical features. It is likely that these compounds have high specific biological activeness, as they contain arsenic in
their structural units, many different kinds of organic radicals, cyanide groups and cuprum (I).


1. One Third Arsine ,2.Arsenic Salt ,3.Cyanide ,4.Copper,5.Thermo-gravimetric Analysis

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A. Vaisberger, E. Pros Kauer, J. Riddick E. Tuns, Organic Solvents. Physical Features and Cleansing Methods. M. il, 1958-5180.

А.S. 629719 Soviet Union. Cleansing Methods of Anhydrids.

R. Gigauri, G. Kamay, M. Ugulava, About the Ethers of Acids. // Аn GSSR. 1970, 60,(3),160.

G. Kamay, R. Gigauri, B. Chernokalskiy, M. Ugulava, New Methods of the Synthesis of Tri-alkyl (aril) of Arsin. / 1971. 41(7) ,1506.

R. Gigauri, G. Chachava, G. Chernikalskyi, M. Ugulava, Synthesis of Phenylene of alkyl-arsin. 1972. 42,1537.

R. Gigauri, M. Injia, B. Chernokalskiy, M. Ugulava, Synthesis of Obtained Arsins//1975. 45, 2179.

R. Gigauri, M. Injia, B. Chernokalskiy, G. Chachava, Synthesis and Change of Anionic Iodide Methyl (α – naphtyl) Alkil-Arsins // -1978. 48,(4), 809.

Chemistry of Pseudo Halogens (from Publishing House of A.M. Golub, K. Keller, V.V. Skopenko). Kiev, “High School”. 1981.

А.S. SSSR. №1453866. G. Abaloniy, V. Kostin, J. Molodikh, N. Anisimova, R. Zakirova, 1988.,22,(02).

G.Peyronel, W. Malavasi, A. Pignedoli , Coppez (1) silver(1) and mersiy (II) Lalide Complexes of the 3.5 – diarsino – 1,2,4,-d dithazolium halides, (thioret hidrohalyds). //,,Speetroehim.acta” 1982, 38, (10) 1069.

Sarauvel I.D., Melkown G. L. //Inorganic Chemistry – 1966,(5), 1909.

R.Morrison, R. Boyde, Organic Chemistry. World. – 1974.

R. K. Freidlyn, Synthetical Methods in Metallurgy. – M. – L: An SSSR. – 1945.

А. К. Babko, I. V, Quantitative Analysis of Chemical Substances. М. 2002.


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